Gruppentransferpolymerisation von Michael-Monomeren: by Friederike Adams

By Friederike Adams

Friederike
Adams untersucht 2-Aminoalkoxybis(phenolat)-Lanthanoid-Komplexe in der Seltenerdmetall-katalysierten
Gruppentransferpolymerisation von Michael-Monomeren. Neu entwickelte
C1-symmetrische Komplexe sind dabei in der Lage, isospezifisch 2-Vinylpyridin
zu polymerisieren. Mechanistische Studien über 13C-NMR-Spektroskopie zeigen, dass
die Katalysatorumgebung dabei stereoregulierend wirkt. Die Autorin führt außerdem
erfolgreich Studien zur C-H-Bindungsaktivierung von Heteroaromaten via
σ-Bindungsmetathese durch, um effizientere Initiatoren in diese Systeme
einzuführen. 

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