The Organometallic Chemistry of N-heterocyclic Carbenes by Han Vinh Huynh

By Han Vinh Huynh

The Organometallic Chemistry of N-heterocyclic Carbenes describes numerous facets of N-heterocyclic Carbenes (NHCs) and their transition steel complexes at an access point appropriate for complex undergraduate scholars and above.

The booklet begins with a ancient assessment at the quest for carbenes and their complexes. in this case, exact houses, reactivities and nomenclature of the 4 classical NHCs derived from imidazoline, imidazole, benzimidazole and 1,2,4-triazole are elaborated. normal and traditionally suitable artificial facets for NHCs, their precursors and complexes are then defined. The e-book maintains with assurance at the practise and features of chosen NHC complexes containing the commonest metals during this zone, i.e. Ni, Pd, Pt, Ag, Cu, Au, Ru, Rh and Ir. The ebook concludes with an summary and outlook at the improvement of varied non-classical NHCs past the 4 classical types.

Topics coated include:

  • Stabilization, dimerization and decomposition of NHCs
  • Stereoelectronic houses of NHCs and their evaluation
  • Diversity of NHCs
  • Isomers of NHC complexes and their identification
  • NMR spectroscopic signatures of NHC complexes
  • normal, irregular and mesoionic NHCs

The Organometallic Chemistry of N-heterocyclic Carbenes is an important source for all scholars and researchers attracted to this more and more very important and renowned box of research.

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