By Rui Shang
This thesis provides the most recent advancements in new catalytic C–C bond formation equipment utilizing simply available carboxylate salts via catalytic decarboxylation with reliable atom economic climate, and applying the sustainable point iron because the catalyst to at once turn on C–H bonds with excessive step potency. during this regard, it explores a mechanistic figuring out of the newly chanced on decarboxylative couplings and the catalytic reactivity of the iron catalyst with assistance from density practical conception calculation.
The thesis is split into elements, the 1st of which makes a speciality of the improvement of a chain of formerly unexplored, reasonably cheap carboxylate salts as helpful development blocks for the formation of varied C–C bonds to entry worthy chemical compounds. In flip, the second one half is dedicated to a number of new C–C bond formation methodologies utilizing the main ubiquitous transition steel, iron, as a catalyst, and utilizing the ever present C–H bond because the coupling partner.
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