Mechanisms in Homogeneous and Heterogeneous Epoxidation by S. Ted Oyama

By S. Ted Oyama

The catalytic epoxidation of olefins performs an immense function within the business construction of a number of commodity compounds, in addition to within the synthesis of many intermediates, nice chemical substances, and prescription drugs. the dimensions of creation levels from thousands of lots in line with yr to some grams consistent with yr. the range of catalysts is big and encompasses all of the identified different types of catalyst variety: homogeneous, heterogeneous, and organic. This publication summarizes the present prestige in those fields targeting premiums, kinetics, and response mechanisms, but additionally covers vast issues together with modeling, computational simulation, technique recommendations, spectroscopy and new catalyst improvement. The similarities and differences among the various response platforms are in comparison, and the most recent advances are described.

* complete directory of epoxide products
* extensive comparability of turnover frequencies of homogeneous, hetergeneous, main-group, biomimetic and organic catalysts
* research of the overall strengths and weaknesses of assorted catalytic systems
* distinctive description of the mechanisms of response for classical and rising catalysts

Show description

Read Online or Download Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis PDF

Similar inorganic chemistry books

Self-Assembled Nanostructures (Nanostructure Science and Technology)

Nanostructures discuss with fabrics that experience suitable dimensions at the nanometer size scales and live within the mesoscopic regime among remoted atoms and molecules in bulk topic. those fabrics have targeted actual homes which are relatively diverse from bulk fabrics. Self-Assembled Nanostructures offers systematic assurance of uncomplicated nanomaterials technological know-how together with fabrics meeting and synthesis, characterization, and alertness.

Transport Properties of Chemicals and Hydrocarbons

Overlaying greater than 7,800 natural and inorganic chemical compounds and hydrocarbons, delivery houses of Chemical and Hydrocarbons, moment variation is a necessary quantity for any chemist or chemical engineer. Spanning gases, beverages, and solids, the publication covers all serious houses (including viscosity, thermal conductivity, and diffusion coefficient).

Anti-Cancer N-Heterocyclic Carbene Complexes of Gold(III), Gold(I) and Platinum(II): Thiol “Switch-on” Fluorescent Probes, Thioredoxin Reductase Inhibitors ... Reticulum Targeting Agents (Springer Theses)

This thesis specializes in the improvement of gold- and non-classical platinum-based anti-cancer brokers that show distinctively assorted anti-cancer mechanisms in comparison to the generally used cisplatin. those steel complexes comprise N-heterocyclic carbene (NHC) ligands that are in a position to shape robust M-C(NHC) bonds, conferring excessive balance and favorable lipophilicity, reactivity and binding specificity of steel complexes on biomolecules.

Modern Applications: Volume 2 (De Gruyter Textbook)

Nuclear chemistry represents a necessary box of easy and utilized research.  sleek functions disguise, for instance, basic points of energetics and high-sensitive, high-selective and non-destructive analytical applied sciences. Nuclear chemistry and radiopharmaceutical chemistry are more and more used to bridge pharmaceutical and scientific learn with cutting-edge non-invasive molecular prognosis in addition to with patient-individual therapy.

Additional info for Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis

Sample text

Download PDF sample

Rated 5.00 of 5 – based on 7 votes