Multifunctional Molecular Magnets Based on by Kenta Imoto

March 4, 2017 by admin

By Kenta Imoto

This thesis demonstrates the unconventional magnetic functionalities in cyanido-bridged steel assemblies, and as such appeals to readers within the box of fabrics technology. The usage of octacyanidometalates as development blocks permits the statement of (i) photo-induced magnetization as a result of a light-induced spin-crossover in an iron octacyanidoniobate-based meeting, (ii) photo-induced magnetization with a two-step spin-crossover habit in an iron octacyanidoniobate-based fabric, and (iii) the coexistence of super-ionic conductivity and metamagnetism in a manganese-octacyanoniobate method. those multi-functionalities are accomplished through incorporating a spin-crossover moiety or a hydrogen-bonding community right into a cyanido-bridged community constitution with a robust magnetic interplay. specifically, in light-induced spin-crossover magnets, a magnetically non-ordered nation may be altered to a magnetically ordered country via photo-irradiation, that's one of many beautiful mechanisms for novel optical switching devices.

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