Multistabile Gitterkomplexe (German Edition) by Benjamin Schneider

March 4, 2017 by admin

By Benjamin Schneider

Die vorliegende Arbeit beschäftigt sich mit der Synthese und Charakterisierung homometallischer (insbesondere Eisen(II,III)) und heterometallischer (Eisen(II,III), Kupfer(I,II), Silber(I)) Gitterkomplexe. Derartige als funktionelle Bausteine für die molekulare Elektronik diskutierten Moleküle wurden mit vielfältigen Methoden (SQUID-Magnetometrie, Cyclovoltammetrie, Mößbauer-Spektroskopie) hinsichtlich ihrer Multistabilität untersucht.
Drei neue Liganden und zwölf neue mehrkernige Komplexe werden vorgestellt, einige von diesen zeigen faszinierende Eigenschaften in der Redoxchemie und dem Spinübergangsverhalten und sind geeignete Kandidaten für die Verwendung in z. B. QCA. Darüber hinaus wurden erste anwendungsbezogene Experimente in Richtung funktionelle Oberflächen mit Hilfe von STM durchgeführt.

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